Geochemistry of Lower Palaeogene bauxites – unique signature of the tectonostratigraphic evolution of a part of the Croatian Karst

Main Article Content

Zoran Peh
Erli Kovačević Galović

Abstract

Investigation of the origin and emplacement of Istrian Lower Paleogene Bauxites (ILPB) discussed in this work relies on the recent perspectives on development of the collision-induced diachronous discontinuity surface in the Istrian part of the Adriatic-Dinaric Carbonate Platform (ADCP). This process, related to the forebulge uplift at the latest stages of Alpine orogenesis, is amply recorded in the geochemical signature of contemporaneous bauxites. In order to elucidate the patterns of bauxite formation a discriminant function model based on the Compositional Data (CoDa) analysis (major and trace elements) is constructed providing the solid ground for separation of the bauxite groups deposited in the subaerially exposed Istrian palaeoenvironment. Complete distinction between the four a priori defined ILPB groups achieved by the analysis demonstrates the highest degree of efficiency in characterizing environmental conditions marked by the unique suite of geochemical variables (compositions). In the last analysis, the current model characteristic for NW compartment of Adriatic South Western Unit (ASWu) is cross-compared with the analogous model of the entire ADCP borrowed from earlier investigation but reconsidered within the CoDa framework. It is done with the purpose of assessing the geochemical correspondence between the two event-markers (ILPB and LPB) and clarifying the nature of tectonostratigraphic constraints, especially with regard to the forebulge development in parts of the Adriatic-Dinaric Carbonate Platform.  

Downloads

Download data is not yet available.

Article Details

Section
Original Scientific Papers
Author Biographies

Zoran Peh, Croatian Geological Survey

department of mineral resources,

senior scientific associate

Erli Kovačević Galović, Croatian Geological Survey

department of mineral resources,

associate researcher

References

AITCHISON, J. (1982): The statistical analysis of compositional data (with discussion).– J. Roy. Stat. Soc. Series B, 44, 139–177.

AITCHISON, J. (1986): The Statistical Analysis of Compositional Data.– Chapman and Hall, London-New York, 416p. doi:10.1002/bimj.4710300705

AITCHISON, J. & EGOZCUE, J.J. (2005): Compositional data analysis: where are we and where should we be heading?– Math. Geol., 37, 829-850. doi:10.1007/s11004-005-7383-7

AITCHISON, J. (2008): The single principle of compositional data analysis, continuing fallacies, confusions and misunderstandings and some suggested remedies.– In: DAUNIS-i-ESTADELLA, J. & MARTÍN-FERNÁNDEZ, J.A. (eds.): Proceedings of CoDaWork'08, the 3rd Compositional Data Analysis Workshop, May 27-30, University of Girona, Girona (Spain), 1-28.

Analytical Methods Committee (1987): Recommendations for the definition, estimation and use of the detection limit.– Analyst, 112, 199-204. doi:10.1039/AN9871200199

ANTWEILER, R.C. & TAYLOR, H.E. (2008): Evaluation of statistical treatments of left-censored environmental data using coincident uncensored data sets: I. Summary statistics.– Environ. Sci. Technol., 42, 3732-3738. doi:10.1021/es071301c.

BALCO, G. & STONE, O.H.J. (2005): Measuring Pleistocene erosion rates with cosmogenic nuclides in buried alluvial sediment, Fisher Valley, southeastern Utah.– Earth Surf. Proc. Land., 30, 1051–1067. doi: 10.1002/esp.1262.

BARCELÓ-VIDAL, C., & PAWLOWSKY-GLAHN, V. (1999): Letter to the Editor: Comment on „Singularity and Nonnormality in the Classification of Compositional Data“ by BOHLING, G.C., DAVIS, J.C., OLEA, R.A. & HARFF, J.– Math. Geol., 31, 581-585.

BLAŠKOVIĆ, I., DRAGIČEVIĆ, I. & POKRAJČIĆ, I. (1989): Tectonic control of the origin of the paleorelief of bauxite deposits in the Western Herzegovina, Yugoslavia.– Travaux ICSOBA, 19 (22), 231-238.

BRLEK, M., KORBAR, T., CVETKO TEŠOVIĆ, B., GLUMAC, B. & FUČEK, L. (2013):
Stratigraphic framework, discontinuity surfaces and regional significance of Campanian slope to ramp carbonates from central Dalmatia, Croatia.– Facies, 59, 779-801.
doi: 10.1007/s10347-012-0342-0

BRLEK, M., KORBAR, T., KOŠIR, A., GLUMAC, B., GRIZELJ, A. & OTONIČAR, B. (2014): Discontinuity surfaces in Upper Cretaceous to Paleogene carbonates of central Dalmatia (Croatia): Glossifungites ichnofacies, biogenic calcretes, and stratigraphic implications.– Facies, 60, 467-487. doi:10.1007/s10347-013-0378-9.

BUCCIANTI, A., MATEU-FIGUERAS, G. & PAWLOWSKY-GLAHN, V. (eds.) (2006): Compositional Data Analysis in the Geosciences: From Theory to Practice.– Geol. Soc. Spec. Publ., The Geological Society London, 264, 224 p.

BUCCIANTI, A. (2013): Is compositional data analysis a way to see beyond the illusion?–Comp. Geosci., 50, 165–173. doi:10.1016/j.cageo.2012.06.012.

CALVERT, S.E. & PEDERSEN, T.F. (1996): Sedimentary geochemistry of manganese; implications for the environment of formation of manganiferous black shales.– Econ. Geol., 91, 36-47. doi:10.2113/gsecongeo.91.1.36.

CRAMPTON, S.L. & ALLEN, P.A. (1995): Recognition of forebulge unconformities associated with early stage foreland basin development; example from the North Alpine foreland basin.– AAPG Bull., 79, 1495-1514.

CVETKO, TEŠOVIĆ. B., GUŠIĆ, I., JELASKA, V. & BUCKOVIĆ, D. (2001): Stratigraphy and microfacies of the Upper Cretaceous Pućišća Formation, Island of Brač, Croatia. Cretaceous Res., 22, 591–613. doi: 10.1006/cres.2001.0279.

CVETKO TEŠOVIĆ, B., GLUMAC, B. & BUCKOVIĆ, D. (2011): Integrated biostratigraphy and carbon isotope stratigraphy of the Lower Cretaceous (Barremian to Albian) Adriatic-Dinaridic carbonate platform deposits in Istria, Croatia.– Cretaceous Res., 32, 301-324. doi:10.1016/j.cretres.2010.12.011.

ĆOSOVIĆ, V., DROBNE, K. & MORO, A. (2004): Paleoenvironmental model for Eocene foraminiferal limestones of the Adriatic carbonate platform (Istrian Peninsula).– Facies, 50, 61-75. doi:10.1007/s10347-004-0006-9.

ĆOSOVIĆ, V., DROBNE, K., OGORELEC, B., MORO, A., KOIĆ, M., ŠOŠTARKO, I., TARLAO, A. & TUNIS, G. (2008): Decastronema barattoloi (DE CASTRO), characteristic fossil of the Palaeocene and the Eocene peritidal sediments from the Adriatic carbonate platform.– Geol. Croat., 61, 321-332.

D’ARGENIO, B. & MINDSZENTY, A. (1995): Bauxites and related palaeokarst: tectonic and climatic event markers at regional unconformities.– Eclogae Geol. Helv., 88, 453–499.

DAUNIS-i-ESTADELLA, J., THIÓ-HENESTROSA, S. & MATEU-FIGUERAS, G. (2011): Two more things about compositional biplots: quality of projection and inclusion of supplementary elements.– In: EGOZCUE, J.J., TOLOSANA-DELGADO, R. & ORTEGO, M.I. (eds.): Proceedings of the 4th International Workshop on Compositional Data Analysis (CoDaWork'11), Girona, 1-14.

DAVIS, J.C. (1986): Statistics and data analysis in geology, 2nd ed.– John Wiley & Sons, New York, 646 p.

DeCELLES, P.G. & GILES, K.A. (1996): Foreland basin systems.– Basin Res., 8, 105-123.

DILLON, W.R., GOLDSTEIN. M. (1984): Multivariate analysis: methods and applications.–John Wiley & Sons, New York, 587 p.

DURN, G., SLOVENEC, D. & ČOVIĆ, M. (2001): Distribution of iron and manganese in terra rossa form Istria and its genetic implications.– Geol. Croat., 54/1, 27-36.

DURN, G., OTTNER, F., TIŠLJAR, J., MINDSZENTY, A. & BARUDŽIJA, U (2003): Regional Subaerial Unconformities in Shallow-Marine Carbonate Sequences of Istria: Sedimentology, Mineralogy, Geochemistry and Micromorphoplogy of Associated Bauxites, Paleosols and Pedo-Sedimentary Complexes. Field Trip P8, 209-254.– In: VLAHOVIĆ, I. & TIŠLJAR, J. (eds): Field Trip Guidebook of 22nd IAS Meeting of Sedimentology, Opatija, 256 p.

EGOZCUE, J.J. & PAWLOWSKY-GLAHN, V. (2006): Simplicial geometry for compositional data.– In: BUCCIANTI, A., MATEU-FIGUERAS, G. & PAWLOWSKY-GLAHN, V. (eds): Compositional Data Analysis in the Geosciences: From Theory to Practice. London: Geol. Soc. Spec. Publ., 264, 145-158.

GARVER, J.J., ROYCE, P.R. & SMICK, T.A. (1996): Chromium and nickel in shale of the Taconic foreland: a case study for the provenance of fine-grained sediments with an ultramafic source.– J. Sediment. Res., 66, 100-106.

GUŠIĆ, I. & JELASKA, V. (1990): Stratigrafija gornjokrednih naslaga otoka Brača u okviru geodinamske evolucije Jadranske karbonatne platforme (Upper Cretaceous stra-tigraphy of the Island of Brač within the geodynamic evolution of the Adriatic carbonate platform).– Djela Jugo-slavenske akademije znanosti i umjetnosti, 69, Institut za geološka istraživanja, Zagreb, 160 p.

HINSBERGEN, D.J.J., MENSINK, M., LANGEREIS, C.G., MAFFIONE, M., SPALLUTO, L., TROPEANO, M. & SABATO, L. (2014): Did Adria rotate relative to Africa?– Solid Earth, 5, 611–629.
doi:10.5194/se-5-611-2014

Hrvatski geološki institut (2009): Geološka karta Republike Hrvatske 1:300000 (Geological Map of the Republic of Croatia 1:300000), Zagreb.

KABATA-PENDIAS, A. & PENDIAS, H. (2001): Trace Elements in Soils and Plants, 3rd ed.– Boca Raton FL, CRC Press, 413 p.

KORBAR, T. (2009): Orogenic evolution of the external Dinarides in the NE Adriatic region; a model constrained by tectonostratigraphy of Upper Cretaceous to Paleogene carbonates.–
Earth-Sci. Rev., 96, 296–312. doi: 10.1016/j.earscirev.2009.07.004.

KORBAR, T., GLUMAC, B., CVETKO TEŠOVIĆ, B. & CADIEUX, S.B. (2012):
Response of a Carbonate Platform to the Cenomanian–Turonian Drowning and OAE 2: a Case Study from the Adriatic Platform (Dalmatia, Croatia).– J. Sediment. Res., 82, 163-176.
doi: 10.2110/jsr.2012/17

KORETSKY, C.M., HAAS, J.R., MILLER, D, & NDENGA, N.T. (2006): Seasonal variations in pore water and sediment geochemistry of littoral lake sediments (Asylum Lake, MI, USA).– Geochemical T. 7(11), 1-26. doi:10.1186/1467-4866-7-11

KOVAČEVIĆ GALOVIĆ, E., ILIJANIĆ, N., PEH, Z., MIKO, S., HASAN, O. (2012): Geochemical discrimination of Early Palaeogene bauxites in Croatia.– Geol. Croat, 65, 53–65. doi: 104154/gc.2012.04

MARTON, E., DROBNE, K., ĆOSOVIĆ, V. & MORO, A. (2003): Palaeomagnetic evidence for Tertiary counterclockwise rotation of Adria.– Tectonophysics, 377, 143–156.
doi:10.1016/j.tecto.2003.08.022

MÁRTON, E., ZAMPIERI, D., GRANDESSO, P., ĆOSOVIĆ, V., & MORO, A. (2010): New Cretaceous paleomagnetic results from the foreland of the Southern Alps and the refined apparent polar wander path for stable Adria.– Tectonophysics, 480, 57–72. doi:10.1016/j.tecto.2009.09.003

MÁRTON, E., ZAMPIERI, D., KÁZMÉR, M., DUNKL, I. & FRISCH, W. (2011): New Paleocene–Eocene paleomagnetic results from the foreland of the Southern Alps confirm decoupling of stable Adria from the African plate.– Tectonophysics, 504, 89-99. doi:10.1016/j.tecto.2011.03.006.

MATIČEC, D., VLAHOVIĆ, I., VELIĆ, I. & TIŠLJAR, J. (1996): Eocene limestones overlying Lower Cretaceous deposits of western Istria (Croatia): did some parts of present Istria form land during the Cretaceous?– Geol. Croat., 49, 117-127.

MINDSZENTY, A., D’ARGENIO, B. & AIELLO, G. (1995): Lithospheric bulges recorded by regional unconformities. The case of Mesozoic – Tertiaty Apulia.– Tectonophysics, 252, 137-161.

MINDSZENTY, A., CSOMA, A., TÖRÖK, Á., HIPS, K. & HERTELENDI, E. (2000): Flexura jellegű előtéri deformációhoz köthető karsztbauxitszintek a Dunántúli-középhegységben (Rudistid limestones, bauxites, paleokarst and geodynamics. The case of the Cretaceous of the Transdanubian Range).– Bull. Geol. Soc. Hung., 131/1-2, 107-152 (in Hungarian with ext. English abstract).

NOCQUET, J.-M. (2012): Present-day kinematics of the Mediterranean: A comprehensive overview of GPS results.– Tectonophysics, 579, 220-242. doi: 10.1016/j.tecto.2012.03.037.

OSMAN, K.T. (ed) (2013): Soils: Principles, Properties and Management.– Springer Science+Business Media, Dordrecht, 271 p. doi: 10.1007/978-94-007-5663-2.

OTONIČAR, B. (2007): Upper Cretaceous to Paleogene forbulge unconformity associated with foreland basin evolution (Kras, Matarsko podolje and Istria; SW Slovenia and NW Croatia).– Acta Carsologica, 36/1, 101–120.

OTONIČAR, B. (2008): Evolution of paleokarst related to a forebulge unconformity; an example from the late Cretaceous and Paleogene of Kras, Matarsko Podolje and Istria, southwest Slovenia and northwest Croatia. –In: SASOWSKY, I.D., FEAZEL, C.T., MYLROIE, J.E., PALMER, A.N. & PALMER, M.V (eds): Karst from Recent to Reservoirs, Karst Waters Institute Special Publication 14, Leesburg, Virginia, 221 p.

PAINE, A.D.M. (1985): 'Ergodic' reasoning in geomorphology: time for a review of the term? – Prog. Phys. Geog., 9, 1-15. doi: 10.1177/030913338500900101.

PAMIĆ, J., GUŠIĆ, I. & JELASKA, V. (1998): Geodynamic evolution of the Central Dinarides.– Tectonophysics, 297, 251–268.

PAMIĆ, J, Balen, D. & Herak, M. (2001): Origin and geodynamic evolution of Late Paleogene magmatic associations along the Periadriatic–Sava–Vardar magmatic belt.– Geodin. Acta, 15, 209–231.

PAWLOWSKY-GLAHN, V. & EGOZCUE, J.J. (2006): Compositional data and their analysis: an introduction.– In: BUCCIANTI A, MATEU-FIGUERAS, G., PAWLOWSKY-GLAHN, V. (eds): Compositional Data Analysis in the Geosciences: From Theory to Practice. Geol. Soc. Spec. Publ., 264, 1-10. DOI: 10.1144/GSL.SP.2006.264.01.01

PEH, Z. & HALAMIĆ, J. (2010): Discriminant function model as a tool for classification of stratigraphically undefined radiolarian cherts in ophiolite zones.– Journal. Geochem. Explor., 107, 30–38. DOI: 10.1016/j.gexplo.2010.06.003.

PEH, Z. & GALOVIĆ, E. (2014): Geochemistry of Istrian Lower Palaeogene bauxites — Is it relevant to the extent of subaerial exposure during Cretaceous times?– Ore Geol Rev., 63, 296-306.

PRELOGOVIĆ, E., KUK, V., JAMIČIĆ, D., ALJINOVIĆ, B. & MARIĆ, K. (1995): Seizmotectonic activity of the Kvarner area (in Croatian).– In: VLAHOVIĆ, I., VELIĆ, I. & ŠPARICA, M. (eds.): Proceedings of the First Croatian Geological Congress, Vol. 2., Croatian Geological Society and Institute of Geology, Zagreb, 487–490.

PRELOGOVIĆ, E., KUK, V., JAMIČIĆ, D., ALJINOVIĆ, B. & MARIĆ, K. (1995): Seizmotectonic activity of the Kvarner area (in Croatian).– In: VLAHOVIĆ, I., VELIĆ, I. & ŠPARICA, M. (eds): Proceedings of the First Croatian Geological Congress, Vol. 2., Croatian Geological Society and Institute of Geology, 487–490.

PRELOGOVIĆ, E., PRIBIČEVIĆ, B., IVKOVIĆ, Ž., DRAGIČEVIĆ, I., BULJAN, R. & TOMLJENOVIĆ, B. (2003): Recent structural fabric of the Dinarides and tectonically active zones important for petroleum-geological exploration in Croatia.– Nafta, 55, 155-161.

QUANTIN, C., ETTLER, V., GARNIER, J. & ŠEBEK, O. (2008): Sources and extractability of chromium and nickel in soil profiles developed on Czech serpentinites. CR. Geosci., 340, 872-882. doi: 10.1016/j.crte.2008.07.013.

REIMANN, C., FILZMOSER, P. & GARRET, R.G. (2004): Background and threshold: critical comparison of methods of determination.– Sci. Total Environ., 346, 1–16.
doi: 10.1016/j.scitotenv.2004.11.023.

REIMANN, C., FILZMOSER, P., FABIAN, K., HRON, K., BIRKE, M., DEMETRIADES, A., DINELLI, E., LADENBERGER, A. & The GEMAS Project Team (2012): The concept of compositional data analysis in practice – Total major element concentrations in agricultural and grazing land soils of Europe.– Sci Total. Environ., 426, 196–210.
doi: 10.1016/j.scitotenv.2012.02.032.

ROCK, N.M.S. (1988): Lecture Notes in Earth Sciences, Vol. 18: Numerical Geology.– Springer Verlag, Berlin, 427 p.

SCISCIANI, V. & CALAMITA, F. (2009): Active intraplate deformation within Adria: Examples from the Adriatic region.– Tectonophysics, 476, 57-72.
doi: 10.1016/j.tecto.2008.10.030.

SAKAČ, K. & ŠINKOVEC, B. (1991): The Bauxites of the Dinarides. Travaux ICSOBA, 20-21, 1-11.

StatSoft, Inc. (2006): STATISTICA (Data Analysis Software System), Version 7.1;
www.statsoft.com2006

STEUBER, T., KORBAR, T., JELASKA, V. & GUŠIĆ, I. (2005): Strontium-isotope stratigraphy of Upper Cretaceous platform carbonates of the island of Brač (Adriatic Sea, Croatia): implications for global correlation of platform evolution and biostratigraphy. Cretaceous Res., 26/5, 741–756.

ŠINKOVEC, B. (1973): The origin of Early Palaeogene bauxites of Istria, Yugoslavia.– Travaux ICSOBA, 3, 151–164.

ŠINKOVEC, B. & SAKAČ, K. (1982): The Paleogene bauxites of Dalmatia.– Travaux ICSOBA, 12, 293-331.

ŠINKOVEC, B. & SAKAČ, K. (1991): Bauxite deposits of Yugoslavia – the state of the Art. Acta Geol. Hung., 34/4, 307–315.

ŠUMANOVAC, F. (2010): Lithosphere structure at the contact of the Adriatic microplate and the Pannonian segment based on the gravity modelling.– Tectonophysics, 485, 94-106.
doi:10.1016/j.tecto.2009.12.005

TARVAINEN, T., REEDER, S. & ALBANESE, S. (2005): Database management and map production.– In: SALMINEN, R., BATISTA, M.J., BIDOVEC, M., DEMETRIADES, A., De VIVO, B., De VOS, W., DURIS, M., GILUCIS, A., GREGORAUSKIENE, V., HALAMIĆ, J., HEITZMANN, P., JORDAN, G., KLAVER, G., KLEIN, P., LIS, J., LOCUTURA, J., MARSINA, K., MAZREKU, A., O'CONNOR, P.J., OLSSON, S.Å., OTTESEN, R.-T., PETERSELL, V., PLANT, J,A,, REEDER, S,, SALPETEUR, I,, SANDSTRÖM, H., SIEWERS, U., STEENFELT, A. & TARVAINEN, T. (eds): Geochemical Atlas of Europe, Part 1, Background Information, Methodology and Maps. Espoo: Geological Survey of Finland, 1-4.

TIEDJE, J.M., SEXSTONE, A.J., PARKIN, T.B. & REVSBECH, N.P. (1984): Anaerobic processes in soil.– Plant Soil, 76, 197-212.

TIŠLJAR, J., VLAHOVIĆ, I., VELIĆ, I., MATIČEC, D. & ROBSON, J. (1998): Carbonate facies evolution from the Late Albian to Middle Cenomanian in southern Istria (Croatia): influence of synsedimentary tectonics and extensive organic carbonate production.– Facies, 38, 37-151.

TOLOSANA-DELGADO, R., OTERO, N. & PAWLOWSKY-GLAHN, V. (2005): Some Basic Concepts of Compositional Geometry.– Math. Geol., 37, 673-680.
doi: 10.1007/s11004-005-7374-8.

TOLOSANA-DELGADO, R. (2012): Uses and misuses of compositional data in sedimentology. Sediment. Geol., 280, 60-79. doi: 10.1016/j.sedgeo.2012.05.005.

VALETON I. (1972): Bauxites, Development in Soil Science 1.– Elsevier Publishing Co., Amsterdam–London–New York, 215 p.

VELIĆ, I., TIŠLJAR, J., MATIČEC, D. & VLAHOVIĆ, I. (1995): A review of the Geology of Istria.– In: VLAHOVIĆ, I. & VELIĆ, I. (eds): Excursion Guidebook, First Croatian Geological Congress, Croatian Geological Society and Institute of Geology, 21-30.

VLAHOVIĆ, I. (1999): Carbonate facies of shallow water depositional systems from Kimmeridgian to Late Albian in western Istria:– Unpubl. PhD thesis (in Croatian with English summary).– University of Zagreb, 327 p.

VLAHOVIĆ, I., TIŠLJAR, J., VELIĆ, I. & MATIČEC, D. (2005): Evolution of the Adriatic carbonate platform: palaeogeography, main events and depositional dynamics.– Palaeogeogr. Palaeocl., 220, 333-360. doi: 10.1016/j.palaeo.2005.01.011.

WILLETT, S.D. (1990): Stochastic inversion of thermal data in a sedimentary basin: resolving spatial variability.– Geophys. J. Int., 103, 321-339.
doi: 10.1111/j.1365-246X.1990.tb01774.x.

YANG, Y. (2011): Tectonically-driven underfilled–overfilled cycles, the middle Cretaceous in the northern Cordilleran foreland basin.– Sediment. Geol., 233, 15-27.
doi: 10.1016/j.sedgeo.2010.10.002.