Preliminary results on degree of thermal alteration recorded in the eastern part of Mt. Papuk, Slavonia, Croatia
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Published:
Jan 14, 2009
Keywords:
Tisia, Mt. Papuk, very low to low-grade metamorphism, Kübler index, Árkai index, b0-parameter, DMSO treatment, geothermobarometry
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Abstract
In order to improve present knowledge of metamorphic conditions to which rocks of the Mt. Papuk have been subjected, selected samples belonging to the Radlovac metamorphic complex as well as overlying sedimentary rocks and parts of Psunj metamorphic complex beneath it were studied. Rocks from Mt. Papuk were investigated, in order to determine thermal conditions, by Kübler index (illite “crystallinity”) and Árkai index (chlorite “crystallinity”) while b0-parameter of K-white mica was used for pressure conditions estimation. Treatment with dimethyl-sulfoxide (DMSO) was used in order to extend application of chlorite “crystallinity” measurements to kaolinite containing samples. Obtained results are: T=250-300°C and P=2-3 kb. Similar T data recorded on various lithologies imply the existence of unknown post lower Triassic thermal event (Alpine very low to low grade metamorphism) affecting different complexes on Mt. Papuk. New data presented and discussed in this paper will set fundament for further research and interpretation of tectono-metamorphic history of the studied area and its correlation with other similar European metamorphic complexes.
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References
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ÁRKAI, P. (1991): Chlorite crystalinity: An empirical aproach and cor-relation with illite crystalinity, coal rocks of northeast Hungary.– J. Metamorph. Geol. 9, 723–734.
ÁRKAI, P., HORVÁTH, Z. & TÓTH, M. (1981): Transitional very low- and low grade metamorphism of the Paleozoic formations, Uppony Mountains, NE–Hungary: mineral assemblages, illite crystallinity, –bo and vitrinite refl ectance data.– Acta Geol. Acad. Sci. Hung., 24, 265–294.
ÁRKAI, P., SASSI, R., ZIRPOLI, G. (1991): On the boundary between the low- and low-grade south-alpine basement in Pustertal: X-ray characterization of the wkite mica in metapelites between Dobbiaco (Toblach, Italy) and Leiten (Austria) (Eastern Alps).– Memorie di scienze geologische, University of Padova, XLIII, 293–304.
ÁRKAI, P., SASSI, F.P., SASSI, R. (1995): Simultaneous measurement of chlorite and illite crystallinity: a more reliable tool for monitoring low- to very low-grade metamorphism in metapelites. A case study from the Southern Alps (NE Italy).– Eur. J. Mineral., 7, 1115–1128.
BIŠEVAC, V., BALOGH, K., BALEN, D. & TIBLJAŠ, D. (2007): New data on metamorphic event in the eastern part of Mt. Papuk, Slavo-nia, Croatia.– In: ROCHA, F., TERROSO, D. & QUINTELA, A. (eds.): EUROCLAY 2007, Abstract Book, Univer sidade de Aveiro, 75–76.
BRKIĆ, M., JAMIČIĆ, D. & PANTIĆ, N. (1974): Karbonske naslage u Papuku (sjeveroistočna Hrvatska) [Carboniferous deposits in Mount Papuk (northeastern Croatia) – in Croatian].– Geol. vjesnik, 27, 53–58.
BUSH, P.R. (1970): A rapid method for determination of carbonate car-bon and organic carbon.– Chem. Geology, 6, 59–62.
CALVERT, C.S. (1984): Simplifi ed, complete CsSl-hydrazine-dimeth-ylsulfoxide intercalation of kaolinite.– Clay. Clay. Miner., 32, 125–130.
CSONTOS, L. (1995): Tertiary tectonic evolution of the Intra-Carpathi-an area: a review.– Acta Vulcanol., 7, 1–13.
FREY, M. (1986): Very-low grade metamorphism of Alps–an introduc-tion.– Schweiz. Mineral. Petrogr. Mitt., 66, 13–27.
GÉCZY, B. (1973): The origin of the Jurassic faunal provinces and the Mediterranean plate tectonics.– Ann. Univ. Sci. Budapest, Eötvös Nom. Sect. Geol., 16, 99–114.
GUIDOTTI, C. & SASSI, F. (1986): Classifi cation and correlation of metamorphic facies series by means of muscovite b0 data from low-grade metapelites.– N. Jb. Mineral. Abh., 157, 363–380.
HAAS, J. & PÉRÓ, C. (2004): Mesozoic evolution of the Tisza Mega-unit.– Int. J. Earth Sci. (Geol. Rundsch.), 93, 297–313.
HUNT (1995): Petroleum Geochemistry and Geology.– W.H. Freeman and Company, New York.
JAMIČIĆ, D. (1983): Strukturni sklop metamorfnih stijena Krndije i južnih padina Papuka [Structural fabric of the metamorphosed rocks of Mt. Krndija and the eastern part of Mt. Papuk – in Croatian].– Geol. vjesnik, 36, 51–72.
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JAMIČIĆ, D. (1995): The role of sinistral strike-slip faults in the forma-tion of the structural fabric of the Slavonian Mts. (Eastern Croatia).– Geol. Croat., 48, 155–160.
JAMIČIĆ, D. & BRKIĆ, M. (1987): Osnovna geološka karta SFRJ 1:100000, list Orahovica [Basic Geological Map of SFRY 1:100000, Orahovica sheet – in Croatian].– Geol. Inst. Zagreb, Fed. Geol. Inst. Beograd.
JAMIČIĆ, D., BRKIĆ, M., CRNKO, J. & VRAGOVIĆ, M. (1987): Os-novna geološka karta SFRJ 1:100000. Tumač za list Orahovica [Ba-sic Geological Map of SFRY 1:100000, Geology of the Orahovica sheet− in Croatian].– Geol. zavod, Zagreb, Sav. geol. zavod, Beograd, 72 p.
JERINIĆ, G., PAMIĆ, J., SREMEC, J. & ŠPANIĆ, D. (1994): First pal-inological and organic-petrographic dana on very low and low-grade metamorphic rocks in Slavonian Mt. (north Croatia).– Geol. Croat., 47, 149–155.
JUDIKK., ÁRKAI, P. HORVÁTH, P., DOBOSI, G., TIBLJAŠ, D., BALEN, D., TOMLJENOVIĆ, B. & †PAMIĆ, J. (2004): Diagen-esis and low-temperature metamorphism of Mt. Medvednica, Cro-atia: Mineral assemblages and phyllosilicate characteristics.– Acta Geol. Hung., 47/2–3, 151–176.
JUDIKK., BALOGH, K., TIBLJAŠ, D. & ÁRKAI, P. (2006): New age data on the low-temperature regional metamorphism of Mt. Med-vednica (Croatia).– Acta Geol. Hung., 49/3, 207–221.
KISCH, H.J. (1990): Calibration of the anchizone: a critical comparison of illite “crystallinity” scales used for defi nition.– J. Metamorph. Geol., 8, 31–46.KISCH, H.J. (1991): Illite “crystalinity”: recommendations on sample preparation, X-ray diffraction settings, and interlaboratory sam-ples.– J. Metamorph. Geol., 9, 665–670.
KISCH, H.J., ÁRKAI, P. & BRIME, C. (2004): On the calibration of the illite Kübler index (illite “crystallinity”).– Schweiz. Mineral. Petrogr. Mitt., 84, 323–331.KRETZ, R. (1983): Symbols for rock-forming minerals.– Am. Mineral., 68, 277–279.
KÜBLER, B. (1964): Les argiles, indicateurs de métamorphisme.– Rev. Inst. Franc. Pétrol., 19, 1093–1112.
KÜBLER, B. (1967): Anchimetamorphisme et schistosite.– Bull. Centre Rech. Pau SNPA 1, 269 – 278.
KÜBLER, B. (1968): Evaluation quantitative du métamorphisme par la cristallinité de I’illite.– Bull. Centre Rech. Pau SNPA 2, 385–397.
KÜBLER, B. (1984): Les indicateurs des transformations physiques et chimiques dans la diagenèse, température et calorimétrie. in: “Ther-mométrie et barométrie géologiques”, Lagache, M. ed. Soc. fr. Minéral. Cristallogr., Paris, 489–596.
KÜBLER B. (1990): “Cristalinité” de I’illite et mixed-layers: breve re-vision.– Schweiz. Mineral. Petrogr. Mitt., 70, 89–93.
KÜBLER, B. & JABOYEDOFF, M. (2000): Illite crystallinity, Compte Rendu de l’Académie des Sciences, Paris.– Earth Planet. Sci., 75–89.PAMIĆ, J. (1986): Magmatic and metamorphic complexes of the adjoin-ing area of the northernmost Dinarides and Pannonian Mass.– Acta Geol. Hung., 29, 203–220.
PAMIĆ, J. (1998): Crystalline basement of the South Pannonian Basin based on surface and subsurface data.– Nafta, Zagreb, 49, 371–390.
PAMIĆ, J. & JAMIČIĆ, D. (1986): Metabasic intrusive rocks from the Paleozoic Radlovac complex of Mt. Papuk in Slavonija (northern Croatia).– Rad JAZU, Zagreb, 424, 97–125.
PAMIĆ, J. & LANPHERE, M. (1991): Hercynian granites and metamor-phic rocks of the Mts. Papuk, Psunj, Krndija and surrounding base-ment of the pannonian Basin, North Croatia (in Croatian).– Geologija, Ljubljana, 34, 81–235.
PAMIĆ, J., LANPHERE, M. & BELAK, M. (1996): Hercynian I–type and S–type granitoids from the Slavonian Mountains (southern Pan-nonian, north Croatia).– N. Jb. Mineral. Abh., 171, 155–186.
PAMIĆ, J. & JURKOVIĆ, I. (2002): Paleozoic tectonostratigraphic units of the northwest and central Dinarides and the adjoining South Tisia.– Int. J. Earth Sci., 91, 538–554.
PAMIĆ, J., BALEN, D. & TIBLJAŠ, D. (2002): Petrology and geochem-istry of orthoamphibolites from the Variscan metamorphic sequenc-es of the South Tisia in Croatia-an overview with geodynamic im-plications.– Int. J. Earth Sci., 91, 787–798.
POTEL, S., FERREIRO MÄHLMANN, R., STERN, W.B., MULLIS, J & FREY, M. (2006): Very low-grade metamorphic evolution of pelitic rocks under high pressure/low temperature conditions, NW Caledonia (SW Pacifi c).– J. Petrol., 47, 991–1015.
RIEDER, M., CAVAZZINI, G., D’YAKONOV, Y., FRANK-KA ME-NETSKII, V., GOTTARDI, G., GUGGENHEIM, S., KOVAL, P., MÜLLER, G., NEIVA, A., RADOSLOVICH, E., ROBERT, J.L., SASSI, F.P., TAKEDA, H., WEISS, Z. & WONES, D. (1998): No-menclature of the micas.– Clay. Clay. Miner., 46, 586–595.
SASSI, F.P. (1972): The petrological and geological signifi cance of the b values of potassic white micas in low-grade metamorphic rocks. An implication to the Eastern Alps. Tschermaks.– Mineral. Petrogr. Mitt., 18, 105–113.
SASSI, F. & SCOLARI, A. (1974): The b value of the potassic white micas as a barometric indicator in low-grade metamorphism of pe-litic schists.– Contr. Mineral. Petrol., 45, 143–152.
SLOVENEC, D. (1986): Nalazi pirofi lita, paragonita, margarita i glau-konita u stijenama slavonskih planina.– Geol. vjesnik, Zagreb, 39, 61–74.
STAMPFLI, G.M., BOREL, G.D., MARCHANT, R. & MOSAR, J. (2002): Western Alps geological constraints on western Tethyan reconstructions.– J. Virt. Explorer, 8, 77–106.
WARR, L. & RICE, H. (1994): Interlaboratory standardization and calibration of clay mineral crystallinity and crystallite size data.– J. Metamorph. Geol., 12, 141–152.
WANG, H., FREY, M. & STERN, W.B. (1996): Diagenesis and metamorphism of clay minerals in the Helvetic Alps of eastern Switzer-land.– Clay. Clay. Miner., 44, 96–11.
ÁRKAI, P. (1991): Chlorite crystalinity: An empirical aproach and cor-relation with illite crystalinity, coal rocks of northeast Hungary.– J. Metamorph. Geol. 9, 723–734.
ÁRKAI, P., HORVÁTH, Z. & TÓTH, M. (1981): Transitional very low- and low grade metamorphism of the Paleozoic formations, Uppony Mountains, NE–Hungary: mineral assemblages, illite crystallinity, –bo and vitrinite refl ectance data.– Acta Geol. Acad. Sci. Hung., 24, 265–294.
ÁRKAI, P., SASSI, R., ZIRPOLI, G. (1991): On the boundary between the low- and low-grade south-alpine basement in Pustertal: X-ray characterization of the wkite mica in metapelites between Dobbiaco (Toblach, Italy) and Leiten (Austria) (Eastern Alps).– Memorie di scienze geologische, University of Padova, XLIII, 293–304.
ÁRKAI, P., SASSI, F.P., SASSI, R. (1995): Simultaneous measurement of chlorite and illite crystallinity: a more reliable tool for monitoring low- to very low-grade metamorphism in metapelites. A case study from the Southern Alps (NE Italy).– Eur. J. Mineral., 7, 1115–1128.
BIŠEVAC, V., BALOGH, K., BALEN, D. & TIBLJAŠ, D. (2007): New data on metamorphic event in the eastern part of Mt. Papuk, Slavo-nia, Croatia.– In: ROCHA, F., TERROSO, D. & QUINTELA, A. (eds.): EUROCLAY 2007, Abstract Book, Univer sidade de Aveiro, 75–76.
BRKIĆ, M., JAMIČIĆ, D. & PANTIĆ, N. (1974): Karbonske naslage u Papuku (sjeveroistočna Hrvatska) [Carboniferous deposits in Mount Papuk (northeastern Croatia) – in Croatian].– Geol. vjesnik, 27, 53–58.
BUSH, P.R. (1970): A rapid method for determination of carbonate car-bon and organic carbon.– Chem. Geology, 6, 59–62.
CALVERT, C.S. (1984): Simplifi ed, complete CsSl-hydrazine-dimeth-ylsulfoxide intercalation of kaolinite.– Clay. Clay. Miner., 32, 125–130.
CSONTOS, L. (1995): Tertiary tectonic evolution of the Intra-Carpathi-an area: a review.– Acta Vulcanol., 7, 1–13.
FREY, M. (1986): Very-low grade metamorphism of Alps–an introduc-tion.– Schweiz. Mineral. Petrogr. Mitt., 66, 13–27.
GÉCZY, B. (1973): The origin of the Jurassic faunal provinces and the Mediterranean plate tectonics.– Ann. Univ. Sci. Budapest, Eötvös Nom. Sect. Geol., 16, 99–114.
GUIDOTTI, C. & SASSI, F. (1986): Classifi cation and correlation of metamorphic facies series by means of muscovite b0 data from low-grade metapelites.– N. Jb. Mineral. Abh., 157, 363–380.
HAAS, J. & PÉRÓ, C. (2004): Mesozoic evolution of the Tisza Mega-unit.– Int. J. Earth Sci. (Geol. Rundsch.), 93, 297–313.
HUNT (1995): Petroleum Geochemistry and Geology.– W.H. Freeman and Company, New York.
JAMIČIĆ, D. (1983): Strukturni sklop metamorfnih stijena Krndije i južnih padina Papuka [Structural fabric of the metamorphosed rocks of Mt. Krndija and the eastern part of Mt. Papuk – in Croatian].– Geol. vjesnik, 36, 51–72.
JAMIČIĆ, D. (1988): Strukturni sklop slavonskih planina (sjeverni Psunj, Papuk, Krndija) [Structural fabric of the Slavonian Mts. (northern Psunj, Papuk, Krndija) – in Croatian]. Unpubl. PhD Thesis, Uni-versity of Zagreb, 152 p.
JAMIČIĆ, D. (1989): Osnovna geološka karta SFRJ 1:100000, list Daru-var [Basic Geological Map of SFRY 1:100000, Daruvar sheet – in Croatian] – Geol. Inst. Zagreb, Fed. Geol. Inst. Beograd.
JAMIČIĆ, D. (1995): The role of sinistral strike-slip faults in the forma-tion of the structural fabric of the Slavonian Mts. (Eastern Croatia).– Geol. Croat., 48, 155–160.
JAMIČIĆ, D. & BRKIĆ, M. (1987): Osnovna geološka karta SFRJ 1:100000, list Orahovica [Basic Geological Map of SFRY 1:100000, Orahovica sheet – in Croatian].– Geol. Inst. Zagreb, Fed. Geol. Inst. Beograd.
JAMIČIĆ, D., BRKIĆ, M., CRNKO, J. & VRAGOVIĆ, M. (1987): Os-novna geološka karta SFRJ 1:100000. Tumač za list Orahovica [Ba-sic Geological Map of SFRY 1:100000, Geology of the Orahovica sheet− in Croatian].– Geol. zavod, Zagreb, Sav. geol. zavod, Beograd, 72 p.
JERINIĆ, G., PAMIĆ, J., SREMEC, J. & ŠPANIĆ, D. (1994): First pal-inological and organic-petrographic dana on very low and low-grade metamorphic rocks in Slavonian Mt. (north Croatia).– Geol. Croat., 47, 149–155.
JUDIKK., ÁRKAI, P. HORVÁTH, P., DOBOSI, G., TIBLJAŠ, D., BALEN, D., TOMLJENOVIĆ, B. & †PAMIĆ, J. (2004): Diagen-esis and low-temperature metamorphism of Mt. Medvednica, Cro-atia: Mineral assemblages and phyllosilicate characteristics.– Acta Geol. Hung., 47/2–3, 151–176.
JUDIKK., BALOGH, K., TIBLJAŠ, D. & ÁRKAI, P. (2006): New age data on the low-temperature regional metamorphism of Mt. Med-vednica (Croatia).– Acta Geol. Hung., 49/3, 207–221.
KISCH, H.J. (1990): Calibration of the anchizone: a critical comparison of illite “crystallinity” scales used for defi nition.– J. Metamorph. Geol., 8, 31–46.KISCH, H.J. (1991): Illite “crystalinity”: recommendations on sample preparation, X-ray diffraction settings, and interlaboratory sam-ples.– J. Metamorph. Geol., 9, 665–670.
KISCH, H.J., ÁRKAI, P. & BRIME, C. (2004): On the calibration of the illite Kübler index (illite “crystallinity”).– Schweiz. Mineral. Petrogr. Mitt., 84, 323–331.KRETZ, R. (1983): Symbols for rock-forming minerals.– Am. Mineral., 68, 277–279.
KÜBLER, B. (1964): Les argiles, indicateurs de métamorphisme.– Rev. Inst. Franc. Pétrol., 19, 1093–1112.
KÜBLER, B. (1967): Anchimetamorphisme et schistosite.– Bull. Centre Rech. Pau SNPA 1, 269 – 278.
KÜBLER, B. (1968): Evaluation quantitative du métamorphisme par la cristallinité de I’illite.– Bull. Centre Rech. Pau SNPA 2, 385–397.
KÜBLER, B. (1984): Les indicateurs des transformations physiques et chimiques dans la diagenèse, température et calorimétrie. in: “Ther-mométrie et barométrie géologiques”, Lagache, M. ed. Soc. fr. Minéral. Cristallogr., Paris, 489–596.
KÜBLER B. (1990): “Cristalinité” de I’illite et mixed-layers: breve re-vision.– Schweiz. Mineral. Petrogr. Mitt., 70, 89–93.
KÜBLER, B. & JABOYEDOFF, M. (2000): Illite crystallinity, Compte Rendu de l’Académie des Sciences, Paris.– Earth Planet. Sci., 75–89.PAMIĆ, J. (1986): Magmatic and metamorphic complexes of the adjoin-ing area of the northernmost Dinarides and Pannonian Mass.– Acta Geol. Hung., 29, 203–220.
PAMIĆ, J. (1998): Crystalline basement of the South Pannonian Basin based on surface and subsurface data.– Nafta, Zagreb, 49, 371–390.
PAMIĆ, J. & JAMIČIĆ, D. (1986): Metabasic intrusive rocks from the Paleozoic Radlovac complex of Mt. Papuk in Slavonija (northern Croatia).– Rad JAZU, Zagreb, 424, 97–125.
PAMIĆ, J. & LANPHERE, M. (1991): Hercynian granites and metamor-phic rocks of the Mts. Papuk, Psunj, Krndija and surrounding base-ment of the pannonian Basin, North Croatia (in Croatian).– Geologija, Ljubljana, 34, 81–235.
PAMIĆ, J., LANPHERE, M. & BELAK, M. (1996): Hercynian I–type and S–type granitoids from the Slavonian Mountains (southern Pan-nonian, north Croatia).– N. Jb. Mineral. Abh., 171, 155–186.
PAMIĆ, J. & JURKOVIĆ, I. (2002): Paleozoic tectonostratigraphic units of the northwest and central Dinarides and the adjoining South Tisia.– Int. J. Earth Sci., 91, 538–554.
PAMIĆ, J., BALEN, D. & TIBLJAŠ, D. (2002): Petrology and geochem-istry of orthoamphibolites from the Variscan metamorphic sequenc-es of the South Tisia in Croatia-an overview with geodynamic im-plications.– Int. J. Earth Sci., 91, 787–798.
POTEL, S., FERREIRO MÄHLMANN, R., STERN, W.B., MULLIS, J & FREY, M. (2006): Very low-grade metamorphic evolution of pelitic rocks under high pressure/low temperature conditions, NW Caledonia (SW Pacifi c).– J. Petrol., 47, 991–1015.
RIEDER, M., CAVAZZINI, G., D’YAKONOV, Y., FRANK-KA ME-NETSKII, V., GOTTARDI, G., GUGGENHEIM, S., KOVAL, P., MÜLLER, G., NEIVA, A., RADOSLOVICH, E., ROBERT, J.L., SASSI, F.P., TAKEDA, H., WEISS, Z. & WONES, D. (1998): No-menclature of the micas.– Clay. Clay. Miner., 46, 586–595.
SASSI, F.P. (1972): The petrological and geological signifi cance of the b values of potassic white micas in low-grade metamorphic rocks. An implication to the Eastern Alps. Tschermaks.– Mineral. Petrogr. Mitt., 18, 105–113.
SASSI, F. & SCOLARI, A. (1974): The b value of the potassic white micas as a barometric indicator in low-grade metamorphism of pe-litic schists.– Contr. Mineral. Petrol., 45, 143–152.
SLOVENEC, D. (1986): Nalazi pirofi lita, paragonita, margarita i glau-konita u stijenama slavonskih planina.– Geol. vjesnik, Zagreb, 39, 61–74.
STAMPFLI, G.M., BOREL, G.D., MARCHANT, R. & MOSAR, J. (2002): Western Alps geological constraints on western Tethyan reconstructions.– J. Virt. Explorer, 8, 77–106.
WARR, L. & RICE, H. (1994): Interlaboratory standardization and calibration of clay mineral crystallinity and crystallite size data.– J. Metamorph. Geol., 12, 141–152.
WANG, H., FREY, M. & STERN, W.B. (1996): Diagenesis and metamorphism of clay minerals in the Helvetic Alps of eastern Switzer-land.– Clay. Clay. Miner., 44, 96–11.