Tracing the origin of raw materials used for the production of ancient ceramics: a case study of multi-period archaeological sites in the Turopolje area (Continental Croatia)

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Natali Neral
Andreja Kudelić
Ana Maričić
Marta Mileusnić

Abstract

The selection of raw materials for ancient pottery production was influenced by a variety of technological and cultural factors, underscoring the importance of characterising these materials to understand the technology of ancient societies. This research examines ancient ceramics from two multi-period archaeological sites: Staro Čiče-Gradišće (Neolithic, Copper Age, Copper/Early Bronze Age, Early Bronze Age, Late Bronze Age, Roman period, and Late Mediaeval period) and Kurilovec-Belinščica (Early Bronze Age and Middle/Late Bronze Age), alongside potential clayey raw materials collected near these settlements. Using a multi-analytical approach (optical microscopy, X-ray powder diffraction, mass and emission spectrometry, and laser granulometry), the research aims to determine the characteristics of the paste recipes (raw clay and tempers) and to examine the type and provenience of the raw materials used for ancient pottery production over different periods of the past (from the Neolithic to the Late Mediaeval period). The results showed that ancient potters preferred to use moderately plastic, sandy clay, while Bronze Age potters often used highly plastic clay. Potters utilised various non-plastic tempering materials, such as sands and gravels, grog, and mollusc shells, with their choice being influenced by the need to enhance technological properties as well as by regional and culturally determined pottery traditions. Most of the ceramics are of local origin, made from easily available raw materials that represent flood sediments of the nearby Sava River. However, non-local materials were detected in Neolithic samples, indicating the presence of exchange networks among those communities.

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ALBERO SANTACREU, D. (2014): Materiality, Techniques and Society in Pottery Production: The Technological Study of Archaeological Ceramics through Paste Analysis. Warsaw, Poland: De Gruyter Open Poland. doi: 10.2478/9783110410204

AMICONE, S., FREUND, K., MANCINI, P., D'ORIANO, R. & BERTHOLD, C. (2020): New insights into Early Iron Age connections between Sardinia and Etruria: Archaeometric analyses of ceramics from Tavolara.-Journal of Archaeological Science: Reports, 33, 102452. 10.1016/j.ja srep.2020.102452

ANDALORO, E., BELFIORE, C., FRANCESCO, A., JACOBSEN, J. & MI TTICA, G. (2011): A preliminary archaeometric study of pottery remains from the archaeological site of Timpone della Motta, in the Sibaritide area (Calabria - southern Italy).-Applied Clay Science, 53(3), 445–453. 10.1016/j.clay.2010.07.021

ARNOLD, D.E. (1985): Ceramic theory and cultural process, New Studies in Archaeology. Cambridge University Press, Cambridge.

ARNOLD, D.E. (2005): Linking society with the compositional analyses of pottery: A model from comparative ethnography. In: LIVINGSTONE SMITH, A., BOSQUET, D. & MARTINEAU R. (eds.): Pottery manufa cturing processes: Reconstitution and interpretation. BAR International Series 1349, Archeopress, Oxford, pp. 15–21.

BALEN-LETUNIĆ, D. (1996): New Late Bronze Age sites from the Zagreb area.– In: ČEČUK, B. (eds.): Archaeological Research in Zagreb and the Zagreb Region and Archaeology and Reconstruction [Novi kasnobrončanodobni lokaliteti sa zagrebačkog područja. U: ČEČUK, B. (ur.): Arheološka istraživanja u Zagrebu i zagrebačkoj regiji i arheologija i obnova – in Croatian]. – Izdanja Hrvatskog arheološkog društva 17, Hrvatsko arheološko društvo, Zagreb, 13–27.

BARUDŽIJA, U., VELIĆ, J., MALVIĆ, T., TRENC, N. & MATOVINOVIĆ BOŽINOVIĆ, N. (2020): Morphometric Characteristics, Shapes and Provenance of Holocene Pebbles from the Sava River Gravels (Zagreb, Croatia).- Geoscience, 10 (92), 1–20.

BASCH, O. (1981): Osnovna geološka karta SFRJ 1:100.000, List Ivanić-Grad L33–81 [Basic Geological Map of SFRY 1:100000, Ivanić-Grad sheet – in Croatian]. – Geološki zavod, Zagreb, Savezni geološki institut, Beograd.

BASCH, O. (1983): Osnovna geološka karta SFRJ 1:100.000, Tumač za list Ivanić-Grad L33–81 [Basic Geological Map of SFRY 1:100000, Geology of the Ivanić-Grad sheet – in Croatian].– Geološki zavod, Zagreb, Savezni geološki institut, Beograd, 66 p.

BELFIORE, C., LA RUSSA, M., BARCA, D., GALLI, G., PEZZINO, A., RUFFOLO, S., VICCARO, M. & FICHERA, G. (2014): A trace element study for the provenance attribution of ceramic artefacts: The case of Dressel 1 amphorae from a late-Republican ship.– Journal of Archaeological Science, 43, 91–104. doi: 10.1016/j.jas.2013.12.015

BELTRAME, M., SITZIA, F., ARRUDA, A., BARRULAS, P., BARATA, F. & MIRAO, J. (2021): The Islamic Ceramic of the Santarém Alcaçova: Raw Materials, Technology, and Trade.– Archaeometry, 63. doi: 10.1111/ arcm.12671

CARLONI, D., ŠEGVIĆ, B., SARTORI, M., ZANONI, G., MOSCARIELLO, A. & BESSE, M. (2021): Raw material choices and material characterization of the 3rd and 2nd millennium BC pottery from the Petit‐Chas seur necropolis: Insights into the megalith‐erecting society of the Upper Rhône Valley, Switzerland.– Geoarchaeology, 36/6, 1009–1044. doi: 10.1002/gea.21867

CROATIAN GEOLOGICAL SURVEY (2009): Geological Map of Republic of Croatia, M 1:300.000. Croatian Geological Survey, Zagreb.

COSTA, M.L., RIOS, G.M., SILVA, M.M.C., SILVA, G.J. & VALDES, U.M. (2011): Mineralogy and chemistry of archaeological ceramic fragments from archaeological dark earth site in Colombian Amazon.– Rev. Esc. Minas, 64/1, 17–23. doi: 10.1590/S0370-44672011000100002

CRNKOVIĆ, B. & BUŠIĆ, M. (1970): Mineraloško-petrografski sastav nano sa rijeke Save [Mineralogical-petrographic composition of Sava River deposits – in Croatian].– In: Zbornik radova RGN fakulteta Sveučilišta u Zagrebu u povodu 30 g. rada (1939–1969), 133–140.

DOLENEC (KRAMAR), S., LUX, J., MLADENOVIC, A., PRISTACZ, H., MIRTIČ, B., SAGADIN, M., ROGAN ŠMUC, N. (2012): Mineralogical and geochemical characteristics of Roman pottery from an archaeological site near Mošnje (Slovenia).– Applied Clay Science, 57, 39–48. doi: 10.1016/j.clay.2011.12.008

DURMAN, A. (1983): "Gradišće" u Starom Čiču – brončanodobni tel ["Gradišće" in Staro Čiče – Bronze Age Tell – in Croatian].– Obavijesti Hrvatskog Arheološkog društva, 15/2, 26–27.

FEDOTOV, G.N., SHEIN, E.V., PUTLYNEV, V.I., ARKHANGEL’SKAYA, T.A., ELISEEV, A.V. & MILANOVSKII, E.Y. (2007): Physicochemical bases of differences between the sedimentometric and laser diffraction techniques of soil particle-size analysis.– Eurasian Soil Science, 40, 281– 288. doi: 10.1134/S1064229307030064

FREESTONE, I., MIDDLETON, A. & MEEKS, N. (1994): Significance of phosphate in ceramic bodies: discussion of paper by Bollong et al.– Journal of Archaeological Science, 21, 425–426.

GONZÁLEZ, I., ROMERO-BAENA, A., GALÁN, E., MIRAS, A., CASTILLA ALCÁNTARA, J.C. & CAMPOS, P. (2018): Ceramic materials from Cuatrovitas archaelogical site (Spain): A mineralogical and chemical study for determining the provenance and the firing temperature.– Applied Clay Science, 166, 38–48. doi: 10.1016/j.clay.2018.09.003

GOSSELAIN, O.A. & LIVINGSTON SMITH, A. (2005): The source: Clay selection and processing practices in sub-Saharan Africa.– In: LIVINGSTONE SMITH, A. BOSQUET, D. & MARTINEAU, R. (eds.): Pottery Manufacturing Processes: Reconstruction and Interpretation. BAR International Series 1349, Archaeopress, Oxford, pp. 33–4.

GUGGENHEIM, S. & MARTIN, R.T. (1995): Definition of clay and clay mineral: joint report of the AIPEA nomenclature and CMS nomenclature committees.– Clay and Clay Minerals, 43/2, 255–256. doi: 10.1346/CCMN.1995.0430213

GUTSUZ, P., KIBAROĞLU, M., SUNAL, G. & HACIOSMANOĞLU, S. (2017): Geochemical characterization of clay deposits in the Amuq Valley (Southern Turkey) and the implications for archaeometric study of ancient ceramics.– Applied Clay Science, 141, 316–333. doi: 10.1016/j.clay.2017.03.004

IONESCU, C., HOECK, V. & GHERGARI, L. (2011): Electron microprobe analysis of ancient ceramics: A case study from Romania.– Applied Clay Science, 53/3, 466–475. doi: 10.1016/j.clay.2010.09.009

IORDANIDIS, A., GARCIA-GUINEA, J. & KARAMITROU-MENTESSIDI, G. (2009): Analytical study of ancient pottery from the archaeologi cal site of Aiani, northern Greece.– Materials Characterization, 60, 292– 302. doi: 10.1016/j.matchar.2008.08.001

KAŁASKA, M., DRUC, I., CHYLA, J., NITA, R., SYCZEWSKI, M., SIUDA, R., MAKOWSKI, K. & GIERSZ, M. (2020): Application of Electron Microprobe Analysis to Identify the Origin of Ancient Pottery Production from the Castillo de Huarmey, Peru.– Archaeometry, 62/6, 1095– 1114. doi: 10.1111/arcm.12581

KREITER, A. (2007): Technological Choices and Material Meanings in Ear ly and Middle Bronze Age Hungary: understanding the active role of material culture through ceramic analysis.– BAR International Series 1604, Oxford.

KUDELIĆ, A. (2016): Kurilovec – Belinščica – brončanodobno naselje u Turopolju [Kurilovec – Belinščica – a Bronze Age Settlement in the Turopolje Region – in Croatian].– Prilozi Instituta za arheologiju 33, 5–52.

KUDELIĆ, A. & SIROVICA, F. (2022): Kurilovec – Belinščica: Tragom brončanodobnog Turopolja / Kurilovec – Belinščica: Tracing the Bronze Age of Turopolje.– In: Monographiae Instituti Archaeologici IX, Institute of Archaeology, Zagreb.

KUDELIĆ, A., MILEUSNIĆ, M., GRZUNOV, A., OTTNER, F. & WRIESNIG, K. (2018): Archaeometry and comparative analysis of the bronze age pottery from Turopolje and Podravina region.– Opvscula Archaeologica, 39, 37–52.

KUDELIĆ, A., NERAL, N. & PARAMAN, L. (2023): Archaeometry of Bronze Age Ceramics from the Area of Trogir.– Vjesnik arheološkog muzeja u Zagrebu, 56/2. doi: 10.52064/vamz.56.2.1

KUREČIĆ, T. (2017): Sedimentologija i paleoekologija pliocenskih viviparus slojeva Vukomeričkih gorica [Sedimentology and paleoecology of Pliocene Viviparus beds from the area of Vukomeričke gorice – in Croatian].– Doctoral thesis, University of Zagreb, Faculty of Science, pp. 153.

MAKO, A., TÓTH, G., WEYNANTS, M., RAJKAI, K., HERMANN, T. & TÓTH, B. (2017): Pedotransfer functions for converting laser diffraction particle-size data to conventional values.– European Journal of Soil Science, 68, 769–782. doi: 10.1111/ejss.12456

MANGE, M. & BEZECZKY, T. (2006): Petrography and provenance of Laecanius Amphorae from Istria, northern Adriatic region, Croatia.– Geoarchaeology, 21, 429–460. doi: 10.1002/gea.20115

MARITAN, L., MAZZOLI, C., NODARI, L. & RUSSO, U. (2005): Second Iron Age grey pottery from Este (northeastern Italy): Study of provenance and technology.– Applied Clay Science, 29. 31–44. doi: 10.1016/j. clay.2004.09.003

MARITAN, L., MAZZOLI, C. & MAZZOCCHIN, S. (2019): Provenance of wine and oil amphorae in northern Adriatic: archaeometric and epigraphic approaches.– ArchéoSciences, 203–210. doi: 10.4000/arche osciences.6732

MARITAN, L., GRAVAGNA, E., CAVAZZINI, G., ZERBONI, A., MAZ ZOLI, C., GRIFA, C., MERCURIO, M., MOHAMED, A., USAI, D. & SALVATORI, S. (2021): Nile River clayey materials in Sudan: Chemical and isotope analysis as reference data for ancient pottery provenance studies.– Quaternary International, 657/1. doi: 10.1016/j.quaint.2021.05.009

MICHELAKI, K., BRAUN, G.V. & HANCOCK, R.G.V. (2014): Local Clay Sources as Histories of Human–Landscape Interactions: A Ceramic Taskscape Perspective.– Journal of Archaeological Method and Theory, 22, 783–827. doi: 10.1007/s10816-014-9204-0

MIŠE, M. & QUINN, P. S. (2022): Origins and Distribution of Hellenistic and Late Republican Transport Amphorae in the Dalmatian Region and its Implications for Adriatic Trade and Economy.– Archaeological and Anthropological Sciences, 14, 225. doi: 10.1007/s12520-022-01689-x

MIŠE, M., SERNEELS, V., MATANA, A., MONTANARI, A. & KIRIGIN, B. (2019): Provenance studies of amphorae from the Greek colony Pharos on the island of Hvar, Croatia.– In: KOEBERL, C. & BICE, D.M. (eds.): 250 million Years of Earth History in Central Italy Celebrating 25 Years of the Geological Observatory of Coldigioco. Geological Society of America Special Paper, 542 p., 471–499. doi: 10.1130/2019.2542(27)

MIŠE, M., QUINN, P., CHARLTON, M., SERNEELS, V. & MONTANARI, A. (2020): Production and circulation of Late Hellenistic fine table ware in Central Dalmatia, Croatia.– Journal of Archaeological Science: Reports, 33, 102537. doi: 10.1016/j.jasrep.2020.102537

MOORE, D.M. & REYNOLDS, R.C. (1997): X-Ray Diffraction and the Identification and Analysis of Clay Minerals. Second edition.– Oxford University Press, New York.

MORENO-MAROTO, J.M. & ALONSO-AZCÁRATE, J. (2018): What is clay? A new definition of “clay” based on plasticity and its impact on the most widespread soil classification systems.– Applied Clay Science, 161, 57–63. doi: 10.1016/j.clay.2018.04.011

NERAL, N., KUDELIĆ, A., MARIČIĆ, A. & MILEUSNIĆ, M. (2023): Pottery technology through time: Archaeometry of pottery and clayey raw material from the multi-period site in eastern Croatia.– The Mining-Geology-Petroleum Engineering Bulletin, 38/2, 1–21. doi: 10.17794/ rgn.2023.2.1

PAPACHRISTODOULOU, C., GRAVANI, K., OIKONOMOU, A. & IOANNIDES, K. (2010): On the provenance and manufacture of red-slipped fine ware from ancient Cassope (NW Greece): Evidence by X-ray ana lytical methods.– Journal of Archaeological Science, 37, 2146–2154. doi: 10.1016/j.jas.2010.02.013

PAVELIĆ, D. (2001): Tectonostratigraphic model for the North Croatian and North Bosnian sector of the Miocene Pannonian Basin System.– Basin Research, 13, 359–376.

PCRG – PREHISTORIC CERAMIC RESEARCH GROUP (2010): The study of later prehistoric pottery: general policies and guidelines for analysis and publication. Prehistoric Ceramic Research Group: Occasional Pa pers, Nos 1 and 2, 3rd Edition Revised 2010.

PIKIJA, M. (1987a): Osnovna geološka karta SFRJ 1:100.000, Tumač za list Sisak L33–93 [Basic Geological Map of SFRY, 1:100000, Geology of the Sisak sheet – in Croatian]. – Geološki zavod, Zagreb, Savezni geološki institut, Beograd, 55 p.

PIKIJA, M. (1987b): Osnovna geološka karta SFRJ 1:100.000, List Sisak L33– 93 [Basic Geological Map of SFRY, 1:100000, Sisak sheet – in Croatian].– Geološki zavod, Zagreb, Savezni geološki institut, Beograd.

POLAKOWSKI, C., SOCHAN, A., BIEGANOWSKI, A., RYŻAK, M., FÖLDÉNYI, R. & TÓTH, J. (2014): Influence of the sand particle shape on particle size distribution measured by laser diffraction method.- International Agrophysics. 28, 195–200.

QUINN, P.S. (2013): Ceramic Petrography – The Interpretation of Archaeo logical Pottery and Related Artefacts in Thin Section. Archaeopress Publishing Ltd, Oxford.

RATTO, N., GOGNI, V., BONOLI ESCOBAR, M. & PLÁ, R. (2015): Mudclay banks and regional geochemistry: The provenance of ceramic raw materials (Department Tinogasta, catamarca, Argentina).- Quaternary International, 375, 13–26. doi: 10.1016/j.quaint.2014.07.018

RICE, P.M. (1987): Pottery Analysis: A source book. The University of Chi cago Press, Chicago & London.
RÖGL, F. & STEININGER, F.F. (1984): Neogene Paratethys, Mediterranean and Indopacific seaways. In: Brenchley, P. (Eds.), Fossils and Climate. John Wiley & Sons, New York, pp. 171–200.

SANTOS RODRIGUES, S.F., DA COSTA, M.L., PÖLLMANN, H., KERN, D.C., IMAZIO DA SILVEIRA, M. & KIPNIS, R. (2015): Pre-historic production of ceramics in the Amazon: Provenience, raw materials, and firing temperatures.- Applied Clay Science, 107, 145–155. doi: 10.1016/j.clay.2015.01.016

SEMIZ, B. (2017): Characteristics of clay-rich raw materials for ceramic ap plications in Denizli region (Western Anatolia).- Applied Clay Science, 137, 83–93. doi: 10.1016/j.clay.2016.12.014

SILLAR, B. & TITE, M.S. (2000): The Challenge of Technological Choices for Materials Science Approaches in Archaeology.- Archaeometry, 42(1), 2–20. doi: 10.1111/j.1475-4754.2000.tb00863.x

SNYDER, R.L. (1992): The use of reference intensity ratios in X-ray quantitative analysis. Powder Diffraction, 7(4), 186–193.

SPATARO, M. (2002): The first farming communities of the Adriatic: Pottery production and circulation in the early and middle Neolithic. Società per la preistoria e protostoria Della regione Friuli-Venezia Giulia, Quaderno 9, Edizioni Svevo Trieste.

SPATARO, M. (2011): A comparison of chemical and petrographic analyses of Neolithic pottery from South-eastern Europe.- Journal of Archaeological Science, 38, 255–269. 10.1016/j.jas.2010.08.026

STERBA, J., SHINOTO, M., SHINZATO, A., ENOMOTO, M. & YOMINE, Y. (2020): Provenancing of pottery from Kamuiyaki Site in East Asia by neutron activation analysis.- Archaeometry, 63 (5). 10.1111/arcm.12627

ŠARIĆ, K., BIKIĆ, V. & ERIĆ, S. (2018): Microstructural, Mineralogical and Petrographical Characteristics of the Medieval Ceramics from the Studenica Monastery (UNESCO World Heritage Site): Implications on the Pottery Technology and Provenance of The Raw Material.- Microscopy and Microanalysis, 24(6), 744–761. doi: 10.1017/S1431927618015349

ŠEGVIĆ, B., ŠEŠELJ, L., SLOVENEC, D., LUGOVIĆ, B., & MAHLMANN, R. F. (2012): Composition, technology of manufacture, and circulation of Hellenistic pottery from the eastern Adriatic: A case study of three archaeological sites along the Dalmatian Coast, Croatia.- Geoarchaeology, 27, 63–87. doi: 10.1002/gea.21379

ŠIKIĆ, K., BASCH, O. & ŠIMUNIĆ, A. (1978): Osnovna geološka karta SFRJ 1:100.000, List Zagreb L33–80 [Basic Geological Map of SFRY, 1:100000, Zagreb sheet – in Croatian].– Institut za geološka istraživanja, Zagreb, Savezni geološki institut, Beograd.

ŠIKIĆ, K., BASCH, O. & ŠIMUNIĆ, A. (1979): Osnovna geološka karta SFRJ 1:100.000, Tumač za list Zagreb L33–80 [Basic Geological Map of SFRY, 1:100000, Geology of the Zagreb sheet – in Croatian].– Institut za geološka istraživanja, Zagreb, Savezni geološki institut, Beograd, 81 p.

ŠIMUNIĆ, A. & BASCH, O. (1975): Stratigraphy of the Quaternary sediments of the Zagreb Posavlje area [Stratigrafija kvartarnih sedimenata zagrebačkog posavlja – in Croatian].– Geološki vjesnik, 28, 153–164.

TEŽAK-GREGL, T. & VOJVODA, P. (1987): Staro Čiče/Gradišće – Multilayered settlement [Staro Čiče/Gradišće – Višeslojno naselje – in Croatian].– Arheološki pregled, 27, 46.

TITE, M.S. (1999): Pottery Production, Distribution, and Consumption – The Contribution of the Physical Sciences.- Journal of Archaeological Method and Theory, 6 (3), 181–233.

VELDE, B. (1992): Introduction to clay minerals: Chemistry, origins, uses and environmental significance. Chapman & Hall, Hong Kong.

VELDE, B. & DRUC, I.C. (1999): Archaeological Ceramic Materials: Origin and Utilization, Springer.

VELDE, B. & MEUNIER, A. (2008): The Origin of Clay Minerals in Soils and Weathered Rocks. Springer.

VELIĆ, J. (1983): Neotectonic relations and development of the western part of the Sava Basin [Neotektonski odnosi i razvitak zapadnog dijela Savske potoline – in Croatian].– Prirodoslovna istraživanja 47, Acta Geologica 13(2), Jugoslavenska akademija znanosti i umjetnosti, Zagreb.

ŽIBRAT GAŠPARIČ, A. (2004): Archaeometrical analysis of Neolithic pottery from the Divaca region, Slovenia.- Documenta Praehistorica, 31. https://doi.org/10.4312/dp.31.15